HCID 54569294, 화합물 → 3-Hexylaniline

HRID 2232414노트

반응식

HRID 2232414 반응식
[CH:1]([C:7]1[CH:8]=[C:9]([N+:13]([O-])=O)[CH:10]=[CH:11][CH:12]=1)=[CH:2][CH2:3][CH2:4][CH2:5][CH3:6].[H][H]>C(O)C.[Pd]>[CH2:1]([C:7]1[CH:8]=[C:9]([CH:10]=[CH:11][CH:12]=1)[NH2:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

참가 물질

5

반응물 2

HCID 54569294HCID 54569294, 화합물HCID 178418361HCID 178418361, 화합물

생성물 1

HCID 5722403-Hexylaniline수율 90.5%

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 702Ethanol용매

실험 절차

The 3-(1-hexenyl)nitrobenzene (11.0 g, 0.054 m) was dissolved in absolute ethanol (500 ml), treated with 1.1 g of 10% palladium on charcoal catalyst and hydrogenated on a Parr apparatus at about 45 psi for 21/2 hours. Hydrogen uptake had ceased. The reaction mixture was filtered to remove catalyst, concentrated under vacuum, and then resulting oil purified by Kuglrohr distillation (BP 75°-85° C. at 0.05 mm Hg) to yield 3-hexylaniline (8.6 g, 90% yield) as a clear colorless oil.

후처리

  1. custom2 hours
  2. filtrationThe reaction mixture was filtered
  3. customto remove catalyst
  4. concentrationconcentrated under vacuum
  5. customresulting oil
  6. distillationpurified by Kuglrohr distillation (BP 75°-85° C. at 0.05 mm Hg)

출처 및 근거

ORD 기록
ord-12db25c0d34f4f5da099e60db4a9b429
출처 데이터셋
uspto-grants-1988_11
특허 번호
US04788209

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