5-(4-chlorophenoxy)pentan-1-ol → 5-(4-Chlorophenoxy)pentanal

HRID 2232623노트

반응식

HRID 2232623 반응식
[Cr](Cl)([O-])(=O)=O.[NH+]1C=CC=CC=1.[Cl:12][C:13]1[CH:25]=[CH:24][C:16]([O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][OH:23])=[CH:15][CH:14]=1>C(Cl)Cl.C(OCC)C>[Cl:12][C:13]1[CH:25]=[CH:24][C:16]([O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH:22]=[O:23])=[CH:15][CH:14]=1

참가 물질

5

반응물 2

HCID 27948975-(4-chlorophenoxy)pentan-1-olHCID 178418287HCID 178418287, 화합물

생성물 1

HCID 232971225-(4-Chlorophenoxy)pentanal

시약·촉매·용매 2

HCID 3283Diethyl Ether용매HCID 6344Dichloromethane용매

실험 절차

To a suspension of 33 g (0.15 mmol) of pyridinium chlorochromate in 450 ml of methylene chloride is added 21.4 g (0.1 mol) of 5-(4-chlorophenoxy)-1-pentanol. The mixture is maintained with stirring for 3 hours, diluted with 900 ml of ethyl ether and stirred for an additional 1 hour.

후처리

  1. temperatureThe mixture is maintained
  2. stirringstirred for an additional 1 hour

출처 및 근거

ORD 기록
ord-2ad751c4f7694c1bbc6610e46fce8578
출처 데이터셋
uspto-grants-1988_11
특허 번호
US04788304

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