Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Diisopropyl Ether → 5-(p-Tolyl)thianthrenium nonafluorobutanesulfonate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Diisopropyl Ether | HCID 7914 | — |
| 반응물 | Trifluoroacetic anhydride | HCID 9845 | — |
| 반응물 | Perfluorobutanesulfonic acid | HCID 67815 | — |
| 반응물 | Thianthrene, 5-oxide | HCID 73220 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | 5-(p-Tolyl)thianthrenium nonafluorobutanesulfonate | HCID 23137824 | — |
반응 단계
Subsequently, 2 g of thianthrene-S-oxide was dissolved in 10 ml of toluene and ice-cooled, and 2.8 ml of trifluoroacetic anhydride and 1.2 ml of nonafluorobutanesulfonic acid were added thereto, followed by stirring for 1 hour. Furthermore, diisopropyl ether was added thereto and after removing the supernatant, the residue was purified through a silica gel column (chloroform/methanol=19/1) to obtain 4.4 g of 5-(p-tolyl)thianthrenium nonafluorobutanesulfonate.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07718344B2 |
| 출처 데이터셋 | uspto-grants-2010_05 |
| ORD ID | ord-0bae235cd23141fa8e786f72bdaf2f18 |
| 출처 메모 | uspto-grants-2010_05 |