Methanamine, N-methyl-, titanium(4+) salt (4:1) → HCID 178423719, 화합물

HRID 2242571노트

반응식

HRID 2242571 반응식
[CH3:1][C:2]1[CH:3]([C:10]2[CH:17]=[CH:16][CH:15]=[CH:14][C:11]=2[CH2:12][OH:13])[C:4]([CH3:9])=[C:5]([CH3:8])[C:6]=1[CH3:7].[CH3:18][N-:19][CH3:20].[CH3:21][N-:22][CH3:23].C[N-]C.C[N-]C.[Ti+4:30]>C1(C)C=CC=CC=1>[CH3:18][N-:19][CH3:20].[CH3:21][N-:22][CH3:23].[CH3:1][C:2]1[CH:3]([C:10]2[CH:17]=[CH:16][CH:15]=[CH:14][C:11]=2[CH2:12][O:13][Ti+2:30])[C:4]([CH3:9])=[C:5]([CH3:8])[C:6]=1[CH3:7]

참가 물질

4

반응물 2

HCID 123185Methanamine, N-methyl-, titanium(4+) salt (4:1)HCID 1317271142-(2,3,4,5-Tetramethylcyclopentadienyl)benzylalcohol

생성물 1

HCID 178423719HCID 178423719, 화합물수율 83.3%

시약·촉매·용매 1

HCID 1140Toluene용매2회

실험 절차

To a solution of 2-(2,3,4,5-tetramethylcyclopentadienyl)benzylalcohol (0.3 g, 1.3 mmol) in toluene (5.2 mL) was added dropwise a solution of tetrakis(dimethylamido)titanium (0.29 g, 1.3 mmol) in toluene (1.7 mL) at −30° C. The mixture was stirred for 30 min at room temperature and then at 110° C. for 5 hrs. The solvent was distilled off to give 2-(2,3,4,5-tetramethylcyclopentadienyl)benzyloxytitanium bis(dimethylamide) (0.30 g, yield 83.3%).

후처리

  1. waitat 110° C. for 5 hrs
  2. distillationThe solvent was distilled off

출처 및 근거

ORD 기록
ord-a8bdc58ffde74794b7d89c6faf3fbb81
출처 데이터셋
uspto-grants-2010_03
특허 번호
US07671226B2

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