4-Hydroxyisophthalaldehyde → 4-[6-(Biphenyl-4-yl)hexyloxy]-1,3-benzenedicarboxaldehyde

반응식

[CH:1]([C:3]1[CH:10]=[C:7]([CH:8]=[O:9])[C:6]([OH:11])=[CH:5][CH:4]=1)=[O:2].S(C1C=CC(C)=CC=1)(O[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][C:22]1[CH:27]=[CH:26][C:25]([C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)=[CH:24][CH:23]=1)(=O)=O>>[C:25]1([C:28]2[CH:29]=[CH:30][CH:31]=[CH:32][CH:33]=2)[CH:24]=[CH:23][C:22]([CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][O:11][C:6]2[CH:5]=[CH:4][C:3]([CH:1]=[O:2])=[CH:10][C:7]=2[CH:8]=[O:9])=[CH:27][CH:26]=1

참가 물질

반응물 2

HCID 1651064-Hydroxyisophthalaldehyde

HCID 199302536-(Biphenyl-4-yl)hexyl tosylate

생성물 1

HCID 199302904-[6-(Biphenyl-4-yl)hexyloxy]-1,3-benzenedicarboxaldehyde

실험 절차

4-[6-(biphenyl-4-yl)hexyloxy]-1,3-benzenedicarboxaldehyde (MS: M+NH4+ =400) was prepared from 5-formyl salicylaldehyde and 6-(biphenyl-4-yl)hexyl tosylate at a temperature of 150° C. using the method in Example 1.

출처 및 근거

ORD 기록: ord-7c10f8c078874c038df927dfc39a7656
출처 데이터셋: uspto-grants-1995_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05428065

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