홈MCP워크벤치Skills
홈워크벤치알림마이페이지
llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
  1. 홈
  2. /반응

Ammonia → Ammonium acrylate acrylic acid

HRID 2245601
노트
인쇄 미리보기

반응식

HRID 2245601 반응식
[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].[NH3:6]>O>[C:1]([O-:5])(=[O:4])[CH:2]=[CH2:3].[NH4+:6].[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

4

반응물 2

HCID 222AmmoniaHCID 6581Acrylic Acid

생성물 1

HCID 19048366Ammonium acrylate acrylic acid

시약·촉매·용매 1

HCID 962Water용매

실험 절차

In 52.96 g of water, was dissolved 28.32 g of a reagent acrylic acid (guaranteed reagent grade manufactured by Wako Pure Chemical Industries, Ltd.). The resulting solution was cooled in an ice bath and slowly mixed with 18.35 g of a 25% by weight aqueous ammonia solution under stirring while keeping the mixture at a temperature of 30° C. or lower to obtain a 40% by weight aqueous ammonium acrylate/acrylic acid=70/30 solution. The aqueous ammonium acrylate/acrylic acid=70/30 solution in an amount of 90 g was brought to 10° C. and purged with nitrogen for 30 minutes, followed by addition of 0.72 g of ammonium carbonate and 0.147 g of triallylamine. To the resulting solution, were added as an initiator 0.1387 g of ammonium persulfate, 0.0322 g of a 30% by weight aqueous hydrogen peroxide solution, and 0.0016 g L-ascorbic acid. Polymerization was performed for one hour to obtain a polymer, which was then crushed and dried at 120° C. for 2 hours in an inert oven with a nitrogen atmosphere. After drying, 100 parts of the polymer was mixed with 0.25 parts of ethyleneglycol diglycidyl ether, 2 parts of water, and 2 parts of ethanol, followed by heat treatment at 120° C. for 60 minutes. The resin obtained as described above was named as a comparative water-absorbing resin (2).

후처리

  1. temperatureThe resulting solution was cooled in an ice bath
  2. customat a temperature of 30° C.

출처 및 근거

ORD 기록
ord-3d8e16bec6df4f5cbc40b0d21aa53b1d
출처 데이터셋
uspto-grants-2010_03
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US07683150B2

반응 노트

불러오는 중…

이 페이지에서참가 물질실험 절차후처리출처 및 근거반응 노트