Diethyl Ether → Silver alpha-methylacetoacetate
반응식
N(CCO)CCO.CCOCC.[CH3:13][CH:14]([C:18]([CH3:20])=[O:19])[C:15]([OH:17])=[O:16].[N+]([O-])([O-])=O.[Ag+:25]>O>[CH3:13][CH:14]([C:18]([CH3:20])=[O:19])[C:15]([O-:17])=[O:16].[Ag+:25]참가 물질
6
실험 절차
Diethanolamine (4.4 g) was dissolved in water (5 mL), and this solution was added to the ether solution of α-methylacetoacetic acid while cooling with ice. A solution of silver nitrate (6.8 g) dissolved in water (8 mL) was then added dropwise. The white precipitate that precipitated was filtered off, washed with ice water and then isopropanol, and then dried, yielding silver α-methylacetoacetate as a white precipitate (yield 4.78 g).
후처리
- temperaturewhile cooling with ice
- additionwas then added dropwise
- customThe white precipitate that precipitated
- filtrationwas filtered off
- washwashed with ice water
- dry with materialisopropanol, and then dried
출처 및 근거
- ORD 기록
- ord-19d0923f799749d287926cd45ed8382b
- 출처 데이터셋
- uspto-grants-2010_03
- 특허 번호
- US07683195B2
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