참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Methyl Isobutyl Ketone | HCID 7909 | — |
| 반응물 | 3,7-Dimethylocta-2,6-Dienal | HCID 8843 | — |
| 촉매 | Zinc acetate (USP) | HCID 2724192 | — |
| 생성물 | 2,8,12-Trimethyl-5,7,11-tridecatrien-4-one | HCID 54329025 | 32.5% |
반응 단계
Into a 2 liter autoclave are charged citral (152 grams), methyl isobutyl ketone (500 grams) and zinc acetate dihydrate (38 grams). The reaction mixture is heated at 160° C. for a period of 12 hours. After filtering the catalyst the organic layer is washed with 10% salt solution. Distillation yielding 76 grams (32% yield) of the product, B.P. 126°-141° C./1 mmHg.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04234518 |
|---|
| 출처 데이터셋 | uspto-grants-1980_11 |
|---|
| ORD ID | ord-7dab42019d5845d293961498223c3dbd |
|---|
| 출처 메모 | uspto-grants-1980_11 |
|---|
