Water → [3-(2-Furyl)phenyl]methanol

HRID 2254445노트

반응식

HRID 2254445 반응식
[O:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[C:6]1[CH:7]=[C:8]([CH:14]=[CH:15][CH:16]=1)[C:9](OCC)=[O:10].[H-].[Al+3].[Li+].[H-].[H-].[H-].O>C(OCC)C>[O:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[C:6]1[CH:7]=[C:8]([CH:14]=[CH:15][CH:16]=1)[CH2:9][OH:10]

참가 물질

5

반응물 3

HCID 962WaterHCID 19744763Ethyl 3-(furan-2-yl)benzoateHCID 21226445Aluminium lithium hydride

생성물 1

HCID 11116545[3-(2-Furyl)phenyl]methanol수율 83%

시약·촉매·용매 1

HCID 3283Diethyl Ether용매2회

실험 절차

Ethyl 3-(2-furyl)benzoate [J. Chem. Soc., (B), 1971, 2305 was dissolved in 5 ml of anhydrous ethyl ether. With stirring under ice cooling, 23 mg of lithium aluminium hydride was added The mixture was stirred for 40 minutes. After the reaction, water and ethyl ether were added to extract the reaction mixture The extract was worked up in a customary manner to give 170 mg (yield 83%) of 3-(2-furyl)benzyl alcohol

후처리

  1. stirringwas stirred for 40 minutes
  2. additionwere added
  3. extractionto extract the reaction mixture The extract

출처 및 근거

ORD 기록
ord-04c96a60e1bb477194670d995865208b
출처 데이터셋
uspto-grants-1993_08
특허 번호
US05234946

반응 노트

불러오는 중…