Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Diethylaluminum chloride → 1-Octene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Diethylaluminum chloride | HCID 7277 | — |
| 반응물 | Heptane | HCID 8900 | — |
| 반응물 | HCID 178418361 | HCID 178418361 | — |
| 생성물 | 1-Octene | HCID 8125 | — |
| 생성물 | 1,7-Octadiene | HCID 19460 | — |
반응 단계
A solution of 106.4 grams (0.95 mole) 1-octene and 5.5 grams (0.0509 mole) 1,7-octadiene (molar charge ratio 95:5) in 450 grams of heptane was polymerized with Et2AlCl (16 millimoles) and AATiCl3 (4.0 millimoles) at 50° C. for 10 hours. During the course of the reaction, hydrogen was bubbled through the reaction mixture. The conversion of the polymer was 65 percent, inherent viscosity was 2.1 dl/gram. The composition of monomers in the copolymer was 97:3 mole ratio from NMR analysis.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05428209 |
| 출처 데이터셋 | uspto-grants-1995_06 |
| ORD ID | ord-058afdbfbf544fed8cd88265b6b3e285 |
| 출처 메모 | uspto-grants-1995_06 |