Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Diethylaluminum chloride → 1-Hexene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Diethylaluminum chloride | HCID 7277 | — |
| 반응물 | Heptane | HCID 8900 | — |
| 반응물 | HCID 178418361 | HCID 178418361 | — |
| 생성물 | 1-Hexene | HCID 11597 | — |
| 생성물 | 1,7-Octadiene | HCID 19460 | — |
반응 단계
A solution of 985.94 grams (11.715 mole) 1-hexene and 58.24 grams (0.4831 mole) 1,7-octadiene (molar charge ratio 96:4) in 450 grams of heptane was polymerized with Et2AlCl (13.5 millimoles) and AATiCl3 (6.97 millimoles) at 25° C. for 20 hours. During the course of the reaction, hydrogen was bubbled through the reaction mixture. The conversion of the polymer was 62 percent, inherent viscosity was 1.6 dl/gram. The composition of monomers in the copolymer was 97.8:2.2 mole ratio from NMR analysis.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05428209 |
| 출처 데이터셋 | uspto-grants-1995_06 |
| ORD ID | ord-c9abef9a5c4546839e88ada6111053af |
| 출처 메모 | uspto-grants-1995_06 |