Diethylaluminum chloride → 1-Octene

HRID 22580

반응식

HRID 22580 반응식
[Al](Cl)([CH2:4][CH3:5])[CH2:2]C.[H][H].[CH3:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15]>>[CH2:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:4][CH3:5].[CH2:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14][CH:15]=[CH2:2]

참가 물질

5

반응물 3

HCID 7277Diethylaluminum chlorideHCID 8900HeptaneHCID 178418361HCID 178418361, 화합물

생성물 2

HCID 81251-OcteneHCID 194601,7-Octadiene

실험 절차

A solution of 416.53 grams (3.711 mole) 1-octene and 8.35 grams (0.0758 mole) 1,7-octadiene (molar charge ratio 98:2) in 450 grams of heptane was polymerized with Et2AlCl (4.14 millimoles) and AATiCl3 (2.75 millimoles) at 25° C. for 26 hours. During the course of the reaction, hydrogen was bubbled through the reaction mixture. The conversion of the polymer was 56 percent, inherent viscosity was 1.3 dl/g. The composition of monomers in the copolymer was 99:1 mole ratio from NMR analysis.

후처리

  1. customwas bubbled through the reaction mixture

출처 및 근거

ORD 기록
ord-cfe8c2df7237419abf87a52f7ed77414
출처 데이터셋
uspto-grants-1995_06
특허 번호
US05428209

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