Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-Indanone → 2-(4-Hexyloxy-benzylidene)-indan-1-one
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-Indanone | HCID 6735 | — |
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | p-(Hexyloxy)benzaldehyde | HCID 79816 | — |
| 용매 | Ethanol | HCID 702 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 2-(4-Hexyloxy-benzylidene)-indan-1-one | HCID 68864867 | — |
반응 단계
1-Indanone (4.17 g, 0.032 mol) was dissolved in ethanol (20 ml), and was added to sodium hydroxide (0.44 g, 0.011 mol) dissolved in water (8 ml) and ethanol (3 ml) and was left to stir for 20 min. 4-(Hexyloxy)benzaldehyde (6.4 ml, 0.031 mol), dissolved in ethanol (35 ml), was added to the mixture and was stirred for 4 hours. The product was isolated by vacuum filtration and was washed with cold ethanol (2×20 ml) and was dried in a vacuum oven. Yield=8.47 g, 85%. 1H NMR and 13C NMR gave expected signals.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06849203B2 |
| 출처 데이터셋 | uspto-grants-2005_02 |
| ORD ID | ord-0a076eed5552481f957a6c3c15c7d65e |
| 출처 메모 | uspto-grants-2005_02 |