Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzoyl Peroxide → Methyl 3-(bromomethyl)benzoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzoyl Peroxide | HCID 7187 | — |
| 반응물 | Benzoic acid, 3-methyl-, methyl ester | HCID 7435 | — |
| 반응물 | N-bromobutanimide | HCID 67184 | — |
| 용매 | Carbon Tetrachloride | HCID 5943 | — |
| 생성물 | Methyl 3-(bromomethyl)benzoate | HCID 517981 | — |
반응 단계
A mixture of 5.5 g (36 mmol) of methyl 3-methylbenzoate, 7.1 g (39.5 mmol) of N-Bromosuccinimide and 0.44 g (1.8 mmol) of benzoyl peroxide in 75 ml of Cl4C is refluxed for 5 h. The solid is filtered and washed with Cl4C. The mother liquors are concentrated and a yellow solid is obtained which is, essentially, monobromated product. This is used in the next step without further purification.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07557212B2 |
| 출처 데이터셋 | uspto-grants-2009_07 |
| ORD ID | ord-be0a5fcfdd5242d0a7929c42ccb8756c |
| 출처 메모 | uspto-grants-2009_07 |