Sodium hexafluorophosphate → 4-Azoniaspiro[3,4]octane hexafluorophosphate

HRID 2263480노트

반응식

HRID 2263480 반응식
[Cl-].[CH2:2]1[N+:5]2([CH2:9][CH2:8][CH2:7][CH2:6]2)[CH2:4][CH2:3]1.[F:10][P-:11]([F:16])([F:15])([F:14])([F:13])[F:12].[Na+]>O>[F:10][P-:11]([F:16])([F:15])([F:14])([F:13])[F:12].[CH2:4]1[N+:5]2([CH2:9][CH2:8][CH2:7][CH2:6]2)[CH2:2][CH2:3]1

참가 물질

4

반응물 2

HCID 5147921Sodium hexafluorophosphateHCID 674420294-Azoniaspiro[3,4]octane chloride

생성물 1

HCID 866231804-Azoniaspiro[3,4]octane hexafluorophosphate수율 70.3%

시약·촉매·용매 1

HCID 962Water용매2회

반응 조건

온도
90 °C

실험 절차

4-Azoniaspiro[3,4]octane chloride solution in water (88 ml) was added over 10 minutes to a solution of sodium hexafluorophosphate (50.3 g) in water (100 ml), followed by a line wash of water (12 ml). Further water (50 ml) was added to aid stirring of the thick suspension. The mixture was heated to 90° C. to aid stirring. The solid was filtered and washed with water (2×100 ml) and dried in a vacuum oven to give 4-azoniaspiro[3,4]octane hexafluorophosphate (54.14 g, 70.3% of theory).

후처리

  1. washwash of water (12 ml)
  2. additionFurther water (50 ml) was added to aid
  3. stirringto aid stirring
  4. filtrationThe solid was filtered
  5. washwashed with water (2×100 ml)
  6. customdried in a vacuum oven

출처 및 근거

ORD 기록
ord-76a967a59e6140068be500339bd29b3a
출처 데이터셋
uspto-grants-2010_12
특허 번호
US07851623B2

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