Ammonia → HCID 59595967, 화합물

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CO[C:3]1[C:8]([N+:9]([O-:11])=[O:10])=[CH:7][CH:6]=[C:5]([C:12]2[O:13][CH:14]=[CH:15][N:16]=2)[N:4]=1.[NH3:17]>>[N+:9]([C:8]1[C:3]([NH2:17])=[N:4][C:5]([C:12]2[O:13][CH:14]=[CH:15][N:16]=2)=[CH:6][CH:7]=1)([O-:11])=[O:10]

참가 물질

반응물 2

HCID 222Ammonia

HCID 59595975HCID 59595975, 화합물

생성물 1

HCID 59595967HCID 59595967, 화합물수율 77%

반응 조건

온도: 100 °C

실험 절차

A suspension of 2-methoxy-3-nitro-6-(1,3-oxazol-2-yl)pyridine (0.187 g, 0.85 mmol) in aqueous ammonia (32%, 5 mL) was heated in a sealed tube to 100° C. with stirring. After 2.5 hours the mixture was cooled and the precipitate was filtered and washed with water and then dried in vacuo to give the title compound (0.134 g, 77%) as a yellow solid.

후처리

temperatureAfter 2.5 hours the mixture was cooled
filtrationthe precipitate was filtered
washwashed with water
customdried in vacuo

출처 및 근거

ORD 기록: ord-bade95ccfb0740ec8e7645ffadde844b
출처 데이터셋: uspto-grants-2010_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07855202B2

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