Thionyl Chloride → Sulfinylperfluorooctaneamide

HRID 227366노트

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HRID 227366 반응식
[S:1](Cl)(Cl)=[O:2].C[Si](C)(C)[N:7]([Si](C)(C)C)[C:8](=[O:31])[C:9]([F:30])([F:29])[C:10]([F:28])([F:27])[C:11]([F:26])([F:25])[C:12]([F:24])([F:23])[C:13]([F:22])([F:21])[C:14]([F:20])([F:19])[C:15]([F:18])([F:17])[F:16]>>[S:1](=[N:7][C:8](=[O:31])[C:9]([F:29])([F:30])[C:10]([F:27])([F:28])[C:11]([F:25])([F:26])[C:12]([F:23])([F:24])[C:13]([F:21])([F:22])[C:14]([F:20])([F:19])[C:15]([F:18])([F:17])[F:16])=[O:2]

참가 물질

3

반응물 2

HCID 24386Thionyl ChlorideHCID 86615112N,N-bis(trimethylsilyl)perfluorooctaneamide

생성물 1

HCID 23161206Sulfinylperfluorooctaneamide

실험 절차

Next, thionyl chloride (SOCl2) 2.4 g was added gradually to N,N-bis(trimethylsilyl)perfluorooctaneamide 12 g in the dry nitrogen atmosphere, which was allowed to react for two hours while being stirred. Then this was distilled and thereby sulfinylperfluorooctaneamide was obtained.

후처리

  1. customto react for two hours
  2. distillationThen this was distilled

출처 및 근거

ORD 기록
ord-780d5624590a4ce0802a7cc83eceee8a
출처 데이터셋
uspto-grants-2009_07
특허 번호
US07560301B2

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