Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
3-Amino-3-(4-nitrophenyl)-2-cyanoacrylonitrile → HCID 59099563, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 3-Amino-3-(4-nitrophenyl)-2-cyanoacrylonitrile | HCID 14027922 | — |
| 반응물 | Diethyldithiophosphate | HCID 53249491 | — |
| 용매 | Ethanol | HCID 702 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | HCID 59099563 | HCID 59099563 | 95% |
반응 단계
A suspension of Example 96C (2.1 g, 9.8 mmol) and 90% diethyl dithiophosphate (1.8 mL, 10.8 mmol) in ethanol (15 mL) and water (15 mL) was heated to reflux for 24 hours, cooled to room temperature, poured into ice water (300 mL), and filtered. The filter cake was dried to provide 2.3 g (95% yield) of the desired product. MS(ESI(−)) m/e 247 (M−H)−.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07560552B2 |
| 출처 데이터셋 | uspto-grants-2009_07 |
| ORD ID | ord-631e3ab4d3404d2c9f8160fcdda6472d |
| 출처 메모 | uspto-grants-2009_07 |