Methoxydiphenylphosphine → HCID 54544134, 화합물

HRID 2285684노트

반응식

[CH3:1][C:2]([CH2:10][CH3:11])([CH2:6][CH2:7][CH2:8][CH3:9])[C:3](Cl)=[O:4].C[O:13][P:14]([C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1)[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1>>[CH3:1][C:2]([CH2:10][CH3:11])([CH2:6][CH2:7][CH2:8][CH3:9])[C:3]([P:14](=[O:13])([C:21]1[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=1)[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1)=[O:4]

참가 물질

반응물 2

HCID 77636Methoxydiphenylphosphine

HCID 227590852-Ethyl-2-methylhexanoyl chloride

생성물 1

HCID 54544134HCID 54544134, 화합물

실험 절차

Using a method similar to that of Example 1, 88 parts of 2-methyl-2-ethylhexanoic acid chloride and 108 parts of methoxydiphenylphosphine give 165 parts of 2-methyl-2-ethylhexanoyl-diphenylphosphine oxide as an oily crude product. Column chromatography over silica gel (eluant: a 3:1 mixture of toluene and ether) gives the product as a pale yellowish oil. Yield 154 parts (90% of theory).

출처 및 근거

ORD 기록: ord-399f50cdad2d403f8f3f3bb360662317
출처 데이터셋: uspto-grants-1982_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04324744

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