Methyl triflate → HCID 15476282, 화합물

HRID 2288572노트

반응식

HRID 2288572 반응식
[CH:1]1[C:14]2[C:5](=[N:6][C:7]3[C:12]([C:13]=2[C:15]([O:17][C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[O:16])=[CH:11][CH:10]=[CH:9][CH:8]=3)[CH:4]=[CH:3][CH:2]=1.[O:24](C)[S:25]([C:28]([F:31])([F:30])[F:29])(=[O:27])=[O:26]>C(Cl)Cl>[F:29][C:28]([F:31])([F:30])[S:25]([O-:27])(=[O:26])=[O:24].[CH3:28][N+:6]1[C:5]2[C:14](=[CH:1][CH:2]=[CH:3][CH:4]=2)[C:13]([C:15]([O:17][C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[O:16])=[C:12]2[C:7]=1[CH:8]=[CH:9][CH:10]=[CH:11]2

참가 물질

4

반응물 2

HCID 9526Methyl triflateHCID 517916Phenyl acridine-9-carboxylate

생성물 1

HCID 15476282HCID 15476282, 화합물

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

Phenyl acridine-9-carboxylate (530 mg, 1.7 mmol) was dissolved in CH2Cl2 (5 mL) under argon and methyl triflate (1 mL, 8.8 mmol) was added. The solution was stirred overnight at room temperature to yield a thick yellow precipitate. This precipitate was filtered, washed with ether and dried to obtain the product as yellow crystals. 1H NMR (acetone-d6) δ 5.22 (s, 3H), 7.47-7.71 (m, 5H), 8.23-9.07 (m, 8H).

후처리

  1. customto yield a thick yellow precipitate
  2. filtrationThis precipitate was filtered
  3. washwashed with ether
  4. customdried

출처 및 근거

ORD 기록
ord-ccd31068837e4f0483912c6297c5bf4a
출처 데이터셋
uspto-grants-2000_07
특허 번호
US06090571

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