Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Tetradecyltrimethylammonium → 2-(2,4-Dichlorophenyl)-2-[1-(1H-1,2,4-triazol-1-yl)cyclopropyl]oxirane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Tetradecyltrimethylammonium | HCID 14251 | — |
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | Iodide Ion | HCID 30165 | — |
| 반응물 | 1-(1H-1,2,4-Triazol-1-yl)cyclopropyl 2,4-dichlorophenyl ketone | HCID 21294612 | — |
| 용매 | 1,1,1-Trichloroethane | HCID 6278 | — |
| 생성물 | 2-(2,4-Dichlorophenyl)-2-[1-(1H-1,2,4-triazol-1-yl)cyclopropyl]oxirane | HCID 20230216 | — |
반응 단계
1-(1-H-1,2,4-Triazol-1-yl)cyclopropyl 2,4-dichlorophenyl ketone (0.5 g, 1.8 mMole) was added to trimethylsulfphoxonium iodide (0.57 g, 2.6 mMole), cetrimide (0.02 g), 1,1,1-trichloroethane (10 ml) and aqueous sodium hydroxide solution (5 ml of 20%). The mixture was refluxed for twenty hours.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04618616 |
| 출처 데이터셋 | uspto-grants-1986_10 |
| ORD ID | ord-cf1b6c86002a44608be900afac2649bc |
| 출처 메모 | uspto-grants-1986_10 |