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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 2292687생성일: 2026년 10월 26일

m-Chloroperbenzoic acid → Ethyl 2-butyl-1-[[2'-carboxy-(1,1'-biphenyl)-4-yl]-methyl]-4-(methylsulphinyl)-1H-imidazole-5-carboxylate

https://huagongshe.com/reaction/2292687

반응식

참여 물질

역할이름HCID투입량
반응물m-Chloroperbenzoic acidHCID 70297—
반응물Ethyl 2-butyl-1-[[2'-(methoxycarbonyl)-(1,1'-biphenyl)-4-yl]-methyl]-4-(methylthio)-1H-imidazole-5-carboxylateHCID 21479063—
생성물Ethyl 2-butyl-1-[[2'-carboxy-(1,1'-biphenyl)-4-yl]-methyl]-4-(methylsulphinyl)-1H-imidazole-5-carboxylateHCID 21479009259.4%

반응 단계

The operation is carried out as in Example 15 starting with 1.55 g of the product obtained in Example 21 using 213 mg of metachloroperbenzoic acid. 1.8 g of crude product is obtained which is chromatographed on silica (eluant: methylene chloride - acetone (7-3)). 1.5 g of desired product is obtained.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US05684028
출처 데이터셋uspto-grants-1997_11
ORD IDord-9a53143639854370b20572afadc2b753
출처 메모uspto-grants-1997_11