Aluminium lithium hydride → HCID 21474721, 화합물
반응식
[CH3:1][N:2]([CH3:17])[C:3]1[CH:4]=[C:5]([CH:14]=[CH:15][CH:16]=1)[O:6][CH2:7][CH:8]([OH:13])[CH2:9][N:10]=[N+]=[N-].[H-].[Al+3].[Li+].[H-].[H-].[H-]>O1CCCC1>[CH3:1][N:2]([CH3:17])[C:3]1[CH:4]=[C:5]([CH:14]=[CH:15][CH:16]=1)[O:6][CH2:7][CH:8]([OH:13])[CH2:9][NH2:10]참가 물질
4
실험 절차
A procedure similar to that described in preparation 13 was repeated, except that 2.41 g of 3-(3-dimethylaminophenoxy)-2-hydroxypropylazide (prepared as described in Preparation 80), 0.76 g of lithium aluminum hydride and 50 ml of anhydrous tetrahydrofuran were used, to give 1.80 g of the title compound having an Rf value of 0.9 (on silica gel thin layer chromatography, using a 4:1 by volume mixture of ethyl acetate and ethanol as the developing solvent).
후처리
- customA procedure similar to that described in preparation 13
출처 및 근거
- ORD 기록
- ord-ae579d516d564ff0a79e83a30dabef24
- 출처 데이터셋
- uspto-grants-1997_11
- 특허 번호
- US05688823
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