Prop-2-en-1-yl 4-aminobenzoate → Allyl 4-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthylacetamido)benzoate

HRID 2294541

반응식

HRID 2294541 반응식
[CH3:1][C:2]1([CH3:18])[CH2:11][CH2:10][C:9]([CH3:13])([CH3:12])[C:8]2[CH:7]=[C:6]([CH2:14][C:15](Cl)=[O:16])[CH:5]=[CH:4][C:3]1=2.[NH2:19][C:20]1[CH:31]=[CH:30][C:23]([C:24]([O:26][CH2:27][CH:28]=[CH2:29])=[O:25])=[CH:22][CH:21]=1>>[CH3:1][C:2]1([CH3:18])[CH2:11][CH2:10][C:9]([CH3:13])([CH3:12])[C:8]2[CH:7]=[C:6]([CH2:14][C:15]([NH:19][C:20]3[CH:21]=[CH:22][C:23]([C:24]([O:26][CH2:27][CH:28]=[CH2:29])=[O:25])=[CH:30][CH:31]=3)=[O:16])[CH:5]=[CH:4][C:3]1=2

참가 물질

3

반응물 2

HCID 13075143Prop-2-en-1-yl 4-aminobenzoateHCID 214744835,6,7,8-Tetrahydro-5,5,8,8-tetramethyl-2-naphthylacetyl chloride

생성물 1

HCID 53900024Allyl 4-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthylacetamido)benzoate

실험 절차

In a manner similar to Example 1(d), by reaction of 4.5 g (16.8 mmol) of 5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthylacetyl chloride with 3 g (16.8 mmol) of allyl 4-aminobenzoate, 5.1 g (75%) of the expected ester are obtained in the form of a slightly yellow oil.

후처리

  1. customare obtained in the form of a slightly yellow oil

출처 및 근거

ORD 기록
ord-cbcda6651985464cb035d3a0624eb4cf
출처 데이터셋
uspto-grants-1997_11
특허 번호
US05688817

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