1-Ethyl-1H-imidazole → N-ethylimidazole bis(trifluoromethylsulfonyl)imide

반응식

[N-:1]([S:9]([C:12]([F:15])([F:14])[F:13])(=[O:11])=[O:10])[S:2]([C:5]([F:8])([F:7])[F:6])(=[O:4])=[O:3].[CH2:16]([N:18]1[CH:22]=[CH:21][N:20]=[CH:19]1)[CH3:17]>>[N-:1]([S:2]([C:5]([F:8])([F:6])[F:7])(=[O:4])=[O:3])[S:9]([C:12]([F:15])([F:14])[F:13])(=[O:11])=[O:10].[CH2:16]([N:18]1[CH:22]=[CH:21][N:20]=[CH:19]1)[CH3:17]

참가 물질

반응물 2

HCID 815401-Ethyl-1H-imidazole

HCID 4176748N-Propyl-Methyl Piperidinium Bis(trifluoroMethylsulfonyl)Imide

생성물 1

HCID 131727537N-ethylimidazole bis(trifluoromethylsulfonyl)imide

실험 절차

To 1.0 g of bis(trifluoromethylsulfonyl)imide was added dropwise 0.34 g of N-ethylimidazole in a nitrogen atmosphere in a glove box, and the solution was stirred overnight to obtain N-ethylimidazole bis(trifluoromethylsulfonyl)imide (EtIm+TFSI−) as a colorless transparent liquid. The resulting salt had a melting point of 6.6° C.

출처 및 근거

ORD 기록: ord-6f3418108ae64076a6578f9a7953d94e
출처 데이터셋: uspto-grants-2009_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07563850B2

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