Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ethyl Acrylate → Methyl 4-nitrononanoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ethyl Acrylate | HCID 8821 | — |
| 반응물 | Potassium Carbonate | HCID 11430 | — |
| 반응물 | 1-Nitrohexane | HCID 12589 | — |
| 촉매 | Trioctylmethylammonium chloride | HCID 21218 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | Methyl 4-nitrononanoate | HCID 10632556 | — |
반응 단계
A suspension of ethyl acrylate, 1-nitrohexane, K2CO3, and Aliquat 336 (6 drops) is sonicated for 5 h. To the reaction is added Et2O. The reaction mixture is filtered, extracted with brine, dried over Na2SO4 (anhydrous), filtered, and concentrated under reduced pressure to give a yellow liquid. The product is purified by column chromatography to give methyl 4-nitrononanoate.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06489323B1 |
| 출처 데이터셋 | uspto-grants-2002_12 |
| ORD ID | ord-a7bd9cc6bcde4f2992d4d3bf87ddc8b3 |
| 출처 메모 | uspto-grants-2002_12 |