Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Butanedione → 3,5-Dimethyl-1-adamantanol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Butanedione | HCID 650 | — |
| 반응물 | 1,3-Dimethyladamantane | HCID 12800 | — |
| 반응물 | 1-Acetyl-3,5-dimethyl-7-adamantanol | HCID 13464074 | — |
| 촉매 | Cobalt diacetate | HCID 6277 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 생성물 | 3,5-Dimethyl-1-adamantanol | HCID 265793 | 17% |
| 생성물 | 1-Acetyl-3,5-dimethyl Adamantane | HCID 12113124 | 8% |
| 생성물 | 1,3-Dimethyl-4-adamantanone | HCID 12644332 | 5% |
반응 단계
A mixture of 3 mmol of 1,3-dimethyladamantane, 9 mmol of biacetyl, 0.0006 mmol of cobalt (II) acetate, and 3 ml of acetic acid was starred at 60° C. under an oxygen atmosphere(1 atm) for 4 hours. Gas chromatographic analysis of products in the reaction mixture demonstrated that 1,3-dimethyladamantane was converted, at a rate of 40%, to 1-acetyl-3,5-dimethyladamantane (yield 8%, selectivity 20%), 1-acetyl-3,5-dimethyl-7-adamantanol (trace), 1,3-dimethyl-5-adamantanol (yield 17%, selectivity 43%), and 1,3-dimethyl-4-adamantanone (yield 5%, selectivity 13%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06429314B1 |
| 출처 데이터셋 | uspto-grants-2002_08 |
| ORD ID | ord-ec44de8e3a9a4717a0249dc9fa12ee5b |
| 출처 메모 | uspto-grants-2002_08 |