Acenaphthylene → 1-Methylthioacenaphthylene

HRID 2302122

반응식

HRID 2302122 반응식
[CH3:1][S:2]SC.[CH:5]1[C:15]2=[C:16]3[C:11](=[CH:12][CH:13]=[CH:14]2)[CH:10]=[CH:9][CH:8]=[C:7]3[CH:6]=1>N1C=CC=CC=1>[CH3:1][S:2][C:6]1[C:7]2=[C:16]3[C:11](=[CH:10][CH:9]=[CH:8]2)[CH:12]=[CH:13][CH:14]=[C:15]3[CH:5]=1

참가 물질

4

반응물 2

HCID 9161AcenaphthyleneHCID 12232Dimethyl Disulfide

생성물 1

HCID 109104981-Methylthioacenaphthylene수율 76%

시약·촉매·용매 1

HCID 1049Pyridine용매

실험 절차

As an example of the benefits that can be realized by use of the two-step procedure, controlled potential electrolysis of dimethyl disulfide in the presence of acenaphthylene in the absence of an organic nucleophilic base resulted in copious polymer formation. But when the same electrolysis procedure was conducted in the additional presence of pyridine, an oxidation-resistant adduct of this invention formed which on eliminative aromatization in the second step resulted in the production of 1-methylthioacenaphthylene in 76% yield using electrochemical reductive elimination.

후처리

  1. customresulted in copious polymer formation
  2. customan oxidation-resistant adduct of this invention formed which on eliminative aromatization in the second step

출처 및 근거

ORD 기록
ord-a1736e7a654148eb9171388fc5a46d30
출처 데이터셋
uspto-grants-2002_08
특허 번호
US06432294B1

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