Cyclohexyl acrylate → p-Tert-butoxystyrene cyclohexyl acrylate

HRID 2302126

반응식

HRID 2302126 반응식
[C:1]([O:5][C:6]1[CH:13]=[CH:12][C:9]([CH:10]=[CH2:11])=[CH:8][CH:7]=1)([CH3:4])([CH3:3])[CH3:2].[C:14]([O:18][CH:19]1[CH2:24][CH2:23][CH2:22][CH2:21][CH2:20]1)(=[O:17])[CH:15]=[CH2:16].N(C(C)(CC)C([O-])=O)=NC(C)(CC)C([O-])=O>O1CCOCC1.CO>[C:1]([O:5][C:6]1[CH:7]=[CH:8][C:9]([CH:10]=[CH2:11])=[CH:12][CH:13]=1)([CH3:4])([CH3:2])[CH3:3].[C:14]([O:18][CH:19]1[CH2:24][CH2:23][CH2:22][CH2:21][CH2:20]1)(=[O:17])[CH:15]=[CH2:16]

참가 물질

6

반응물 3

HCID 18298Cyclohexyl acrylateHCID 5775311-(Tert-butoxy)-4-ethenylbenzeneHCID 219175032,2'-Azobis(methyl 2-methylpropanate)

생성물 1

HCID 86587325p-Tert-butoxystyrene cyclohexyl acrylate

시약·촉매·용매 2

HCID 887Methanol용매HCID 312751,4-Dioxane용매

실험 절차

To 50 g (0.284 mole) of p-tert-butoxystyrene and 43.8 g (0.284 mole) of cyclohexyl acrylate was added 3 g of 2,2′-azobis(methyl 2-methylpropionate), followed by conducting a polymerization reaction in 1,4-dioxane under nitrogen gas streams at 80° C. for 6 hours. After cooling, the reaction solution was poured in 5000 ml of aqueous methanol solution to precipitate out. Crystal was recovered by filtration and dried under reduced pressure to give 89.2 g of poly(p-tert-butoxystyrene/cyclohexyl acrylate) as white powdery crystal. A weight-average molecular weight of the polymer was about 21000 by GPC measurement using polystyrene as a standard.

후처리

  1. temperatureAfter cooling
  2. customto precipitate out
  3. filtrationCrystal was recovered by filtration
  4. customdried under reduced pressure

출처 및 근거

ORD 기록
ord-d810103e678f47d596aee3a7c20b8322
출처 데이터셋
uspto-grants-2002_08
특허 번호
US06432608B1

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