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Methyl vinyl ketone → 4-acetyl-1,2-dimethylcyclohexene

HRID 2304375
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인쇄 미리보기

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HRID 2304375 반응식
[CH3:1][C:2]([C:4]([CH3:6])=[CH2:5])=[CH2:3].[CH:7]([C:9]([CH3:11])=[O:10])=[CH2:8]>>[C:9]([CH:7]1[CH2:8][CH2:5][C:4]([CH3:6])=[C:2]([CH3:1])[CH2:3]1)(=[O:10])[CH3:11]
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참가 물질

3

반응물 2

HCID 6570Methyl vinyl ketoneHCID 105662,3-Dimethyl-1,3-butadiene

생성물 1

HCID 110081164-acetyl-1,2-dimethylcyclohexene

실험 절차

The reaction between 2,3-dimethylbutadiene and methyl vinyl ketone was performed in substantially the same manner as in Example 45, except that each of the compounds synthesized in Examples 42 to 44 was individually used as the Lewis acid catalyst. The yields of the reaction product (i.e., 4-acetyl-1,2-dimethylcyclohexene) are shown in Table 1.

출처 및 근거

ORD 기록
ord-5548b6dd0cba4907985001bd60d0078d
출처 데이터셋
uspto-grants-2002_08
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US06436866B1

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