참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 1-Dodecyl glycidyl ether | HCID 17163 | — |
| 반응물 | Sodium Bicarbonate | HCID 516892 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 1-O-Dodecylglycerol | HCID 97774 | — |
반응 단계
In an autoclave, 249 of the resulting dodecyl glycidyl ether, 97.2 g of water and 34.8 g of sodium bicarbonate were charged and were stirred at 200° C. for 8 hours. After completion of the reaction, the reaction mixture was dehydrated at 120° C. under reduced pressure (6.67 kPa), followed by purification by distillation under reduced pressure (13 to 26 Pa, 160 to 170° C.), whereby 117 g of monododecyl glyceryl ether was obtained. As a result of gas chromatographic analysis (hereinafter abbreviated as “GLC”), it was found that the resulting product had a purity not less than 99% and the content of a chlorohydrin ether isomer different in alcohol added position and a 2-mole adduct of epichlorohydrin (hereinafter called “organochlorine compounds”, for simplicity) was not greater than 100 ppm.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US06437196B1 |
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| 출처 데이터셋 | uspto-grants-2002_08 |
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| ORD ID | ord-9629739e041b4f1c80d810c998b33259 |
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| 출처 메모 | uspto-grants-2002_08 |
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