Tetrahydropyran → Ethyl tetrahydro-2H-pyran-2-ylacetate

HRID 2305354노트

반응식

[CH3:1][CH2:2][O:3]/[C:4](/[O-:8])=[CH:5]/[N+]#N.[O:9]1[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10]1>>[O:9]1[CH2:14][CH2:13][CH2:12][CH2:11][CH:10]1[CH2:5][C:4]([O:3][CH2:2][CH3:1])=[O:8]

참가 물질

반응물 2

HCID 8894Tetrahydropyran

HCID 178472844HCID 178472844, 화합물

생성물 1

HCID 558877Ethyl tetrahydro-2H-pyran-2-ylacetate

실험 절차

Following the procedure of Preparative Example 14, 2.0 g (17.5 mmol) of ethyl diazo acetate was reacted with tetrahydropyran to give 1.75 g of the product as a colorless oil, bp 95°-106° C. at 20 mm Hg.

출처 및 근거

ORD 기록: ord-fca9b260458d45cb9a1c7223ec674f68
출처 데이터셋: uspto-grants-2002_08
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06440974B2

반응 노트

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