Diethyl (1-cyanoethyl)phosphonate → 2-(3,3,5,5-Tetramethylcyclohexylidene)propionitrile

참여 물질

역할	이름	HCID	투입량
반응물	Diethyl (1-cyanoethyl)phosphonate	HCID 282103	—
반응물	3,3,5,5-Tetramethylcyclohexylideneacetonitrile	HCID 22630150	—
생성물	2-(3,3,5,5-Tetramethylcyclohexylidene)propionitrile	HCID 22630158	41%

반응 단계

Prepared according to the procedure for compound 20 (Example 10, a) using diethyl (1-cyanoethyl)phosphonate. Nitrile 21 obtained as a colorless oil with 41% yield. 1H-NMR: (CDCl3, TMS): 0.96 and 1.00 (total 12H, both s, c-Hex-3,5-CH3); 1.34 (2H, s, c-Hex-4-CH2); 1.91 (3H, s, propionitrile-3-CH3); 2.04 and 2.28 ppm (total 4H, both s, c-Hex-2,6-CH2).

출처 및 근거

DOI	10.6084/m9.figshare.5104873.v1
특허 번호	US06828462B2
출처 데이터셋	uspto-grants-2004_12
ORD ID	ord-21238243ee2d4cc49273a5b3675f7004
출처 메모	uspto-grants-2004_12