Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Triphenylarsine oxide → Triphenylarsine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Triphenylarsine oxide | HCID 14382 | — |
| 반응물 | 1-(1-Naphthyl)-2-naphthol | HCID 2755260 | — |
| 반응물 | Isopropanolate | HCID 3260420 | — |
| 반응물 | Lanthanum isopropoxide | HCID 9858075 | — |
| 생성물 | Triphenylarsine | HCID 11773 | — |
반응 단계
A complex according to the invention is synthesized as follows. At first, lanthanum isopropoxide is used as a metal isopropoxide and triphenyl arsinoxide is used as triphenyl oxide. Lanthanum isopropoxide, optically active binaphtol (BINOL derivative) and triphenyl arsinoxide are mixed at a ratio of 1:1:1 mol % in an argon atmosphere at room temperature for 30 minutes to 1 hour to obtain La-BINOL derivative-Ph3As═O complex.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06833442B2 |
| 출처 데이터셋 | uspto-grants-2004_12 |
| ORD ID | ord-e1c1d0fcdc914041ae80d3801c7ca936 |
| 출처 메모 | uspto-grants-2004_12 |