Ethanol → Manganese Lysocellin

HRID 2309218노트

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HRID 2309218 반응식
[Na].[CH3:2][CH2:3][C@@H:4]([C:25]([C@H:27]([C@@H:29]([OH:45])[C@H:30]([C@H:32]1[O:37][C@@H:36]([CH2:38][C:39]([O:41][OH:42])=[O:40])[C@H:35]([CH3:43])[CH2:34][C@@H:33]1[CH3:44])[CH3:31])[CH3:28])=[O:26])[C@H:5]1[O:9][C@@:8]([C@:11]2([OH:23])[O:15][C@@:14]([C@@H:18]([OH:21])[CH2:19][CH3:20])([CH2:16][CH3:17])[CH2:13][C@H:12]2[CH3:22])([CH3:10])[CH2:7][C@@H:6]1[CH3:24].[Cl-].[Mn+2:47].[Cl-].C(O)C>O>[Mn:47].[CH3:2][CH2:3][C@@H:4]([C:25]([C@H:27]([C@@H:29]([OH:45])[C@H:30]([C@H:32]1[O:37][C@@H:36]([CH2:38][C:39]([O:41][OH:42])=[O:40])[C@H:35]([CH3:43])[CH2:34][C@@H:33]1[CH3:44])[CH3:31])[CH3:28])=[O:26])[C@H:5]1[O:9][C@@:8]([C@:11]2([OH:23])[O:15][C@@:14]([C@@H:18]([OH:21])[CH2:19][CH3:20])([CH2:16][CH3:17])[CH2:13][C@H:12]2[CH3:22])([CH3:10])[CH2:7][C@@H:6]1[CH3:24]

참가 물질

5

반응물 3

HCID 702EthanolHCID 10313134Manganese(2+) dichlorideHCID 86741790Sodium lysocellin

생성물 1

HCID 86741789Manganese Lysocellin

시약·촉매·용매 1

HCID 962Water용매

실험 절차

A mixture of 6.5 g sodium lysocellin, 2.0 g manganese chloride and 100 ml of 90% ethanol was stirred and held at ambient temperature for 18 hours. Stirring was continued and water added slowly to precipitate a tacky semi-solid. Removal of the mother liquor by decantation and trituration of the residue with fresh water gave a filterable amorphous solid which was isolated and dried (6.4 g). The product had a melting point of 112.8° C. Analysis: Calculated % Mn (4.19); Found (3.75).

후처리

  1. stirringStirring
  2. customto precipitate a tacky semi-solid
  3. customRemoval of the mother liquor by decantation and trituration of the residue with fresh water
  4. customgave a filterable amorphous solid which
  5. customwas isolated
  6. customdried (6.4 g)

출처 및 근거

ORD 기록
ord-99fd22a8361e40da86a45ff3e0fba804
출처 데이터셋
uspto-grants-1987_09
특허 번호
US04693992

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