Samarium → Anthracene

HRID 231204

반응식

HRID 231204 반응식
[Sm].[CH:2]1[C:15]2[C:6](=[CH:7][C:8]3[C:13]([CH:14]=2)=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH:5]=[CH:4][CH:3]=1.[Yb]>COCCOC>[CH:5]1[C:6]2[C:15](=[CH:14][C:13]3[C:8]([CH:7]=2)=[CH:9][CH:10]=[CH:11][CH:12]=3)[CH:2]=[CH:3][CH:4]=1

참가 물질

4

반응물 2

HCID 23951SamariumHCID 20034756Anthracene ytterbium

생성물 1

HCID 8418Anthracene

시약·촉매·용매 1

HCID 80711,2-Dimethoxyethane용매

실험 절차

Example 1 is repeated, but with the use of 20 m.g atoms of samarium powder instead of ytterbium. Anthracene samarium (1/1) solvated with DME, is obtained as a purple compound with a substantially quantitative yield with respect to anthracene. The complex, treated with a water excess, gives dihydroanthracene with a quantitative yield.

출처 및 근거

ORD 기록
ord-5448869b772e453abe847c556d786061
출처 데이터셋
uspto-grants-1989_07
특허 번호
US04845201

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