Methanol → 9,10-Dihydroanthracene
반응식
[CH:1]1[C:14]2[C:5](=[CH:6][C:7]3[C:12]([CH:13]=2)=[CH:11][CH:10]=[CH:9][CH:8]=3)[CH:4]=[CH:3][CH:2]=1.[Ce].CO>COCCOC>[CH:4]1[C:5]2[CH2:6][C:7]3[C:12](=[CH:11][CH:10]=[CH:9][CH:8]=3)[CH2:13][C:14]=2[CH:1]=[CH:2][CH:3]=1참가 물질
5
실험 절차
1.14 mmole of anthracene is reacted with 4.57 m atoms of cerium as powder in 7.5 ml of DME in the conditions of example 9 with application of ultrasound, thus producing anthracenecerium. After action of a methanol excess and the usual treatment, 9,10-dihydroanthracene was isolated with a yield of 59%.
후처리
- customthus producing anthracenecerium
출처 및 근거
- ORD 기록
- ord-4d94dcbf8d314500877ef0fa80aacbef
- 출처 데이터셋
- uspto-grants-1989_07
- 특허 번호
- US04845201
반응 노트
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