Ethanolamine → 2-(beta-Hydroxyethyl)amino-6-(beta-hydroxyethyl)amino-4-chloronitrobenzene

HRID 231374노트

반응식

HRID 231374 반응식
Cl[C:2]1[CH:7]=[C:6]([Cl:8])[CH:5]=[C:4](Cl)[C:3]=1[N+:10]([O-:12])=[O:11].[CH2:13]([CH2:15][NH2:16])[OH:14]>>[Cl:8][C:6]1[CH:5]=[C:4]([NH:16][CH2:15][CH2:13][OH:14])[C:3]([N+:10]([O-:12])=[O:11])=[C:2]([NH:16][CH2:15][CH2:13][OH:14])[CH:7]=1

참가 물질

3

반응물 2

HCID 700EthanolamineHCID 292282,4,6-Trichloronitrobenzene

생성물 1

HCID 200710912-(beta-Hydroxyethyl)amino-6-(beta-hydroxyethyl)amino-4-chloronitrobenzene

실험 절차

0.132 mole (30 g) of 2,4,6-trichloronitrobenzene is heated to 95° C. in 120 ml of ethanolamine. After 30 minutes, the reaction medium is poured into 240 g of an ice-water mixture. The product expected precipitates. It is drained, washed with water and then dried under vacuum in the presence of phosphorous pentoxide. After recrystallizing from absolute ethanol, it melts at 154° C.

후처리

  1. customThe product expected precipitates
  2. washwashed with water
  3. dry with materialdried under vacuum in the presence of phosphorous pentoxide
  4. customAfter recrystallizing from absolute ethanol, it melts at 154° C.

출처 및 근거

ORD 기록
ord-0b6c28dde6634d2b8761689383ed485d
출처 데이터셋
uspto-grants-1989_07
특허 번호
US04845293

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