Ammonia → HCID 20071066, 화합물

HRID 231375노트

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HRID 231375 반응식
Cl[C:2]1[CH:7]=[C:6]([Cl:8])[CH:5]=[C:4]([NH:9][CH3:10])[C:3]=1[N+:11]([O-:13])=[O:12].[NH3:14]>O.C(O)C>[Cl:8][C:6]1[CH:5]=[C:4]([NH:9][CH3:10])[C:3]([N+:11]([O-:13])=[O:12])=[C:2]([NH2:14])[CH:7]=1

참가 물질

5

반응물 2

HCID 222AmmoniaHCID 20071071HCID 20071071, 화합물

생성물 1

HCID 20071066HCID 20071066, 화합물

시약·촉매·용매 2

HCID 702Ethanol용매HCID 962Water용매

실험 절차

0.034 mole (7.5 g) of 2,4-dichloro-6-methylaminonitrobenzene is added to 100 ml of a 28% solution of ammonia in water and 50 ml of ethanol in an autoclave. The reaction medium is heated for 12 hours at 145°-150° C., the pressure being 12 kg/cm2. The product expected precipitates from the reaction medium on cooling. After draining and re-impasting in water, it is dried by heating under vacuum in the presence of phosphorous pentoxide. Recrystallized from isopropanol, it melts at 129° C.

후처리

  1. temperatureThe reaction medium is heated for 12 hours at 145°-150° C.
  2. customThe product expected precipitates from the reaction medium
  3. temperatureon cooling
  4. customit is dried
  5. temperatureby heating under vacuum in the presence of phosphorous pentoxide
  6. customRecrystallized from isopropanol, it melts at 129° C.

출처 및 근거

ORD 기록
ord-a4fe7d87c5e74771a36a028cfe2c8f13
출처 데이터셋
uspto-grants-1989_07
특허 번호
US04845293

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