Hematoporphyrin → HCID 131715999, 화합물
반응식
[CH3:1][C:2]1[C:20]([CH:21]([OH:23])[CH3:22])=[C:19]2[NH:24][C:3]=1[CH:4]=[C:5]1[C:38]([CH3:39])=[C:37]([CH2:40][CH2:41][C:42]([OH:44])=[O:43])[C:7]([CH:8]=[C:9]3[N:13]=[C:12]([CH:14]=[C:15]4[C:26]([CH:27]([OH:29])[CH3:28])=[C:25]([CH3:30])[C:17](=[CH:18]2)[NH:16]4)[C:11]([CH3:31])=[C:10]3[CH2:32][CH2:33][C:34]([OH:36])=[O:35])=[N:6]1>C1COCC1.C1CCC(NC2CCCCC2)CC1.CCOCC>[CH3:1][C:2]1[C:20]([CH:21]([OH:23])[CH3:22])=[C:19]2[NH:24][C:3]=1[CH:4]=[C:5]1[C:38]([CH3:39])=[C:37]([CH2:40][CH2:41][C:42]([OH:44])=[O:43])[C:7]([CH:8]=[C:9]3[N:13]=[C:12]([CH:14]=[C:15]4[C:26]([CH:27]([OH:29])[CH3:28])=[C:25]([CH3:30])[C:17](=[CH:18]2)[NH:16]4)[C:11]([CH3:31])=[C:10]3[CH2:32][CH2:33][C:34]([OH:36])=[O:35])=[N:6]1.[CH2:20]1[CH2:19][CH2:18][CH:17]([NH:16][CH:15]2[CH2:14][CH2:12][CH2:28][CH2:27][CH2:26]2)[CH2:25][CH2:30]1참가 물질
5
실험 절차
To a solution of hematoporphyrin (1 g) in THF (30 ml), DCHA (2 ml) dissolved in ether (10 ml) was added, whereby the reaction proceeded. Ether was added to the reaction mixture. The precipitated crystals were collected by filtration and washed with ether to give hematoporphyrin DCHA salt (1.4 g). Yield, 90.0%.