Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4-tert-Butylcyclohexanone → Cyclohexane, 1-(1,1-dimethylethyl)-4-methylene-
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4-tert-Butylcyclohexanone | HCID 7392 | — |
| 반응물 | Tetrahydrofuran | HCID 8028 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 용매 | Hexane | HCID 8058 | — |
| 생성물 | Cyclohexane, 1-(1,1-dimethylethyl)-4-methylene- | HCID 139425 | 70% |
반응 단계
BDAM (3.00 grams) was suspended in 40 milliliters of methylene chloride and 2 molar equivalents of THF were added at 0° C. After a homogeneous solution was formed, 1 molar equivalent of TEAL in 10 milliliters of hexane was added followed by 2.20 grams of 4-tert-butylcyclohexanone. After overnight stirring, reaction mixture was hydrolyzed and worked up as described in Example 1. A total of 1.50 grams of 4-tert-butyl-1-methylenecyclohexane was isolated (70% yield).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04849574 |
| 출처 데이터셋 | uspto-grants-1989_07 |
| ORD ID | ord-e97d4a423c634dc3b47fab2cc27e75c0 |
| 출처 메모 | uspto-grants-1989_07 |