Glyphosate → N-tert-Butylglycine

HRID 231983

반응식

HRID 231983 반응식
P(CNCC(O)=O)(O)(O)=O.[C:11]([N:15](CP(O)(O)=O)[CH2:16][C:17]([OH:19])=[O:18])([CH3:14])([CH3:13])[CH3:12].C(N)(C)(C)C>>[C:11]([NH:15][CH2:16][C:17]([OH:19])=[O:18])([CH3:14])([CH3:13])[CH3:12]

참가 물질

4

반응물 3

HCID 3496GlyphosateHCID 6385Tert-ButylamineHCID 21917312N-t-butyl-N-phosphonomethylglycine

생성물 1

HCID 414246N-tert-Butylglycine

실험 절차

Gaertner, U.S. Pat. No. 3,927,080, describes the production of N-phosphonomethylglycine by acid-catalyzed dealkylation of N-t-butyl-N-phosphonomethylglycine or its esters. Tertiary butylamine is reacted with a bromoacetate ester to produce an ester of N-t-butylglycine which is in turn reacted with formaldehyde and phosphorous acid to produce the N-t-butyl-N-phosphonomethylglycine precursor.

출처 및 근거

ORD 기록
ord-6c338ea2cef04f129300214f89b16608
출처 데이터셋
uspto-grants-1989_07
특허 번호
US04851131

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