Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → HCID 178418251, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | 2-Butyl-4-chloro-5-(hydroxymethyl)imidazole | HCID 2735662 | — |
| 촉매 | HCID 178418406 | HCID 178418406 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | HCID 178418251 | HCID 178418251 | 86.3% |
반응 단계
A stirred mixture of 2-n-butyl-4-chloro-5-hydroxymethylimidazole (15.00 g, 0.0795 mol) and activated manganese dioxide (40.00 g) in 600 ml of methylene chloride was refluxed for 24 h using a water separator. The mixture was filtered hot through a Celite® pad. The Celite® pad was washed several times with hot methylene chloride. The washings were combined with the filtrate and concentrated in vacuo to give 12.81 g (86%) of the aldehyde as a white solid; mp 97°-98° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05728842 |
| 출처 데이터셋 | uspto-grants-1998_03 |
| ORD ID | ord-0fdf59899d7d46d0ae418ee316a592b9 |
| 출처 메모 | uspto-grants-1998_03 |