Rhodium → Rhodium Tribenzylphosphine

HRID 2351107노트

반응식

HRID 2351107 반응식
[Rh:1].[CH2:2]([P:9]([CH2:17][C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1>CC(C(O)C(COC(C(C)C)=O)(C)C)C>[Rh:1].[CH2:17]([P:9]([CH2:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1)[CH2:10][C:11]1[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=1)[C:18]1[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=1

참가 물질

4

반응물 2

HCID 23948RhodiumHCID 82101Phosphine, tris(phenylmethyl)-

생성물 1

HCID 86743422Rhodium Tribenzylphosphine

시약·촉매·용매 1

HCID 6490Texanol용매

반응 조건

온도
125 °C

실험 절차

A catalyst charge comprised of 31.25 mg of rhodium (as rhodium 2-ethylhexanoate) and varying amounts of tribenzylphosphine (as noted in Table 3) dissolved in 0.2 liter of Texanol® solvent was charged to the reactor system described above. The reactor was maintained at 125° C. and operated continuously for seven hours. The reaction was conducted according to the general procedure set forth above. Operating parameters and reaction results are set forth in Table 3.

후처리

  1. additionA catalyst charge
  2. additionwas charged to the reactor system
  3. customOperating parameters and reaction
  4. customresults

출처 및 근거

ORD 기록
ord-ba968caa234e46b0b608476ce3c94700
출처 데이터셋
uspto-grants-1989_10
특허 번호
US04871878

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