Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Undecanenitrile → 2-Decyl-2-oxazoline
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Undecanenitrile | HCID 16722 | — |
| 반응물 | Dodecanenitrile | HCID 17092 | — |
| 반응물 | Acetaldehyde ammonia | HCID 522583 | — |
| 촉매 | Cadmium acetate, dihydrate | HCID 6537495 | — |
| 용매 | 1-Butanol | HCID 263 | — |
| 생성물 | 2-Decyl-2-oxazoline | HCID 14651789 | 64.3% |
반응 단계
Undecyl cyanide in Example 1 was substituted with 18.13 g (108.4 mmoles) of undecanenitrile and allowed to react with 7.5 ml (121.3) mmoles of aminoethanol in presence of cadmium acetate dihydrate (667 mg; 2.5 mmoles) in 1-butanol under identical reaction conditions. The reaction mixture was worked up following Example 1 and the residue was distilled at 118°-120°/1.2 mm to give 14.72 g (64.3%) of 2-decyl-2oxazoline.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04876249 |
| 출처 데이터셋 | uspto-grants-1989_10 |
| ORD ID | ord-b31973048aac46f39b5157a3a9eac804 |
| 출처 메모 | uspto-grants-1989_10 |