2,2-Bis(4-nitrobenzyl)-1,3 di(6-bromohexanoyl)propanediol → HCID 178447907, 화합물

HRID 2354275

반응식

HRID 2354275 반응식
[N+:1]([C:4]1[CH:41]=[CH:40][C:7]([CH2:8][C:9]([CH2:30][C:31]2[CH:36]=[CH:35][C:34]([N+:37]([O-:39])=[O:38])=[CH:33][CH:32]=2)([CH2:21][C:22](=[O:29])[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27]Br)[C:10]([C:13](=[O:20])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18]Br)([OH:12])[OH:11])=[CH:6][CH:5]=1)([O-:3])=[O:2].[CH2:42]([C@H:45]1[CH2:50][CH2:49][C@H:48]([C:51]2[CH:56]=[CH:55][C:54]([OH:57])=[CH:53][CH:52]=2)[CH2:47][CH2:46]1)[CH2:43][CH3:44]>>[N+:1]([C:4]1[CH:41]=[CH:40][C:7]([CH2:8][C:9]([CH2:30][C:31]2[CH:36]=[CH:35][C:34]([N+:37]([O-:39])=[O:38])=[CH:33][CH:32]=2)([CH2:21][C:22](=[O:29])[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][O:57][C:54]2[CH:55]=[CH:56][C:51]([C@H:48]3[CH2:49][CH2:50][C@H:45]([CH2:42][CH2:43][CH3:44])[CH2:46][CH2:47]3)=[CH:52][CH:53]=2)[C:10]([C:13](=[O:20])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][O:57][C:54]2[CH:55]=[CH:56][C:51]([C@H:48]3[CH2:47][CH2:46][C@H:45]([CH2:42][CH2:43][CH3:44])[CH2:50][CH2:49]3)=[CH:52][CH:53]=2)([OH:12])[OH:11])=[CH:6][CH:5]=1)([O-:3])=[O:2]

참가 물질

3

반응물 2

HCID 229285982,2-Bis(4-nitrobenzyl)-1,3 di(6-bromohexanoyl)propanediolHCID 178447901HCID 178447901, 화합물

생성물 1

HCID 178447907HCID 178447907, 화합물

실험 절차

The preparation was carried out analogously to Synthesis Example 4 using 3.14 g (4.48 mmol) 2,2-bis(4-nitrobenzyl)-1,3 di(6-bromohexanoyl)propanediol and 1.96 g (8.98 mmol 4-(trans-4-propylcyclohexyl)phenol yield 2,2-bis(4-nitrobenzyl)-1,3-di {6-[4-(trans-4-propylcyclohexyl)phenoxy]hexanoyl}propanediol.

출처 및 근거

ORD 기록
ord-6ff2ce62cd1a46de8a579eec5f277901
출처 데이터셋
uspto-grants-2010_07
특허 번호
US07750185B2

연결된 노트

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