Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
6-Methylquinoline → 4-Quinolinecarboxaldehyde
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 6-Methylquinoline | HCID 7059 | — |
| 반응물 | 4-Methylquinoline | HCID 10285 | — |
| 반응물 | 2,6-Dimethylquinoline | HCID 13414 | — |
| 반응물 | Selenium Dioxide | HCID 24007 | — |
| 반응물 | 6-Quinolinecarbaldehyde | HCID 765653 | — |
| 생성물 | 4-Quinolinecarboxaldehyde | HCID 78072 | — |
| 생성물 | 6-Methyl-2-quinolinecarboxaldehyde | HCID 14645230 | — |
반응 단계
6-Methylquinoline-2-carboxaldehyde and quinoline-4-carboxaldehyde were prepared from 2,6-dimethylquinoline and 4-methylquinoline respectively by selenium dioxide oxidation following essentially the same procedures as those described in Organic Reactions, vol 24, ch. 4. Quinoline-6-carboxaldehyde was similarly prepared from 6-methylquinoline following essentially the same procedure as that described in J. Gen. chem. USSR, 1944, 14, 330 (Chem. Abstr., 1945, 39, 40772)
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04640708 |
| 출처 데이터셋 | uspto-grants-1987_02 |
| ORD ID | ord-6a821a3559c24adf8b998b18f4b3561a |
| 출처 메모 | uspto-grants-1987_02 |