Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
P-Cresol → Sodium p-methylphenolate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | P-Cresol | HCID 2879 | — |
| 반응물 | Sodium hydride | HCID 24758 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | Sodium p-methylphenolate | HCID 23673456 | — |
반응 단계
4-methylphenol (3.73 g, 0.035 mol) is dissolved in 10 mL THF and added dropwise to a suspension of sodium hydride (0.83 g, 0.035 mol) in 60 mL THF to produce sodium 4-methyl phenoxide. HOC6H4SO2NNaSO2CF3 (4.06 g, 0.012 mol) is dissolved in 50 mL THF and added dropwise to a suspension of sodium hydride (0.30 g, 0.012 mol) and tetra(n-butyl)ammonium bromide (0.4 g) in 50 mL THF and stirred for 16 hours to produce a sodium phenoxide solution of the sulfonimide NaOC6H4SO2NNaSO2CF3.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07763702B2 |
| 출처 데이터셋 | uspto-grants-2010_07 |
| ORD ID | ord-1f19c5352ad24cc3a2ea2dbeb8abaf07 |
| 출처 메모 | uspto-grants-2010_07 |