Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzaldehyde, 3,5-dimethyl- → N-[(3,5-Dimethylphenyl)methylene]-N-[2-(diphenylphosphino)ethyl]amine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzaldehyde, 3,5-dimethyl- | HCID 34225 | — |
| 반응물 | (2-Aminoethyl)diphenylphosphine | HCID 273264 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | N-[(3,5-Dimethylphenyl)methylene]-N-[2-(diphenylphosphino)ethyl]amine | HCID 59390145 | 98% |
반응 단계
Under argon, a solution of 2-diphenylphosphino-ethylamine (652.2 mg, 2.84 mmol) and 3,5-dimethyl-benzaldehyde (387.4 mg, 2.89 mmol) in ethanol (15 mL) was heated at 65° C. (oil bath) for 4 h. Then, the solvent was removed in-vacuo to give the desired product (>98% by 1H-NMR) as a colourless oil (993.2 mg, 2.8 mmmol, quantitative).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07763758B2 |
| 출처 데이터셋 | uspto-grants-2010_07 |
| ORD ID | ord-cfa24e65e3b74f51aca3b505b58e1af8 |
| 출처 메모 | uspto-grants-2010_07 |