반응식
C(=O)([O:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)OC.Cl[C:13]1[CH:18]=[CH:17][C:16]([C:19]([F:22])([F:21])[F:20])=[CH:15][C:14]=1[N+:23]([O-:25])=[O:24].CC1C(CN2CCC(N3CCC(N4C(=O)NC5C4=CC=CC=5)CC3)CC2)=CC=CC=1.C(=O)([O-])[O-]>>[C:5]1([O:4][C:13]2[CH:18]=[CH:17][C:16]([C:19]([F:22])([F:21])[F:20])=[CH:15][C:14]=2[N+:23]([O-:25])=[O:24])[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1참가 물질
5
반응 조건
- 온도
- 150 °C
실험 절차
A mixture of 3.8 g of methyl phenyl carbonate, 5.64 g of 4-chloro-3-nitrobenzotrifluoride, and 0.17 g of TBPB was heated at 150° C. for 1 hour. All of the carbonate was converted with a 99 percent yield of 2-nitro-4-trifluoromethylphenyl phenyl ether. Distillation of the product yielded 6.65 g (94 percent) of the ether, b.p. 148°-9° C./2 mm.
출처 및 근거
- ORD 기록
- ord-98fb5941a208442cbdd380a63fbbe737
- 출처 데이터셋
- uspto-grants-1987_02
- 특허 번호
- US04642349
연결된 노트
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